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41.
42.
Dr. Ma Su Dr. Yan Shi Minghui Wang Ruixuan Gao Jianfeng Wu Hai Xu Chuanwu Xi Prof. Jianfeng Cai 《ChemMedChem》2019,14(23):1963-1967
Host Defense Peptides (HDPs) have gained considerable interest due to the omnipresent threat of bacterial infection as a serious public health concern. However, development of HDPs is impeded by several drawbacks, such as poor selectivity, susceptibility to proteolytic degradation, low-to-moderate activity and requiring complex syntheses. Herein we report a class of lipo-linear α/urea-γ-AApeptides with a hybrid backbone and low molecular weight. The heterogeneous backbone not only enhances chemodiversity, but also shows effective antimicrobial activity against Gram-positive bacteria and is capable of disrupting bacterial membranes and killing bacteria rapidly. Given their low molecular weight and ease of access via facile synthesis, they could be practical antibiotic agents. 相似文献
43.
Xiaochao Liu Yuejun Liu Jian Yang Wenzhi Wang Dengwang Lai Long Mao Wei Zheng Jun Yang Xi Chen 《应用聚合物科学杂志》2019,136(21):47504
Polyamide 6–66 (PA6-66)–montmorillonite (MMT)–nanosilica (NS) nanocomposite films were fabricated through a cast film process and then biaxially stretched on a laboratory stretcher. Uniaxial or biaxial stretching induced the elongated conformation of MMT and NS. The b axis of the α crystals and the amorphous phase were revealed to align along the machine direction (MD) after stretching, with the uniaxial orientation playing a more significant role. Furthermore, the crystallinity of PA6-66 stretching increased with the stretching ratio. Uniaxial stretching gave rise to a significantly enhanced tensile strength along the MD, whereas it slightly decreased the mechanical properties along the transverse direction (TD). In contrast, the films subjected to biaxial stretching exhibited more balanced mechanical properties. Uniaxial and biaxial stretching led to decreased transmittance and increased haze in the PA6-66–MMT–NS films; this could have been due to the elongated nanostructure of the two nanofillers, which inhibited the transmission and facilitated the scattering of visible light. The thermal shrinkage of the films increased with increasing stretching ratio, and the biaxially oriented films presented nearly equal shrinkage in the MD and TD. The addition of nanofillers decreased the shrinkage attributed to the mobility inhibition of the polymer chains during heating. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47504. 相似文献
44.
现有的属性约简方法大部分关注决策系统中的所有决策类,而在实际决策过程中决策者往往仅关注决策系统中的一种或几种决策类。针对上述问题,提出基于多特定决策类的不完备决策系统正域约简的理论框架。首先,给出不完备决策系统单特定决策类正域约简的概念;第二,将单特定决策类正域约简推广到多特定决策类,构造了相应的差别矩阵及区分函数;第三,分析并证明了相关定理,提出基于差别矩阵的不完备决策系统多特定决策类正域约简算法(PRMDM);最后,选取4组UCI数据集进行实验。在数据集Teaching-assistant-evaluation、House、Connectionist-bench和Cardiotocography上,基于差别矩阵的不完备决策系正域约简算法(PRDM)的平均约简长度分别为4.00、13.00、9.00和20.00,PRMDM算法(多特定决策类中决策类数目为2)的平均约简长度分别为3.00、8.00、8.00和18.00。实验结果验证了PRMDM算法的有效性。 相似文献
45.
46.
The enhanced photocatalytic activity of Na0.9Mg0.45Ti3.55O8 co‐loaded with silver and platinum 下载免费PDF全文
Jing‐Zhou Wang Ze‐Qing Guo Jian‐Ping Zhou Yu‐Xi Lei Xuan‐Xuan Shi Qadeer Ul Hassan 《国际能源研究杂志》2018,42(3):1056-1065
Noble metals Ag and Pt were loaded on Na0.9Mg0.45Ti3.55O8 (NMTO) by chemical bath deposition method, which was synthesized firstly in our recent work. The scanning electron microscopy and transmission electron microscopy results show that Ag and Pt nanoparticles were distributed on the different surfaces of NMTO. NMTO loaded with Ag and Pt can efficiently enhance the separation of photogenerated electron‐hole pairs, exhibiting much higher photodegradative ability for methylene blue and rhodamine B than the pure NMTO. The best weight concentrations of Ag and Pt are 9.00% and 3.70%, respectively. The electrostatic field is built in the Schottky barrier between NMTO and noble metals, leading to the energy band bending. Then, photogenerated electrons and holes are efficiently separated to enhance the photocatalytic activity. 相似文献
47.
Lin Haicheng Huang Wantong Zhao Kun Qiao Shuang Liu Zheng Wu Jian Chen Xi Ji Shuai-Hua 《Nano Research》2020,13(1):133-137
Nano Research - The isostructural and isoelectronic transition-metal-dichalcogenides 1T-TaS2 and 1T-TaSe2 are layered materials with intricate electronic structures. Combining the molecular beam... 相似文献
48.
One‐Step Construction of N,P‐Codoped Porous Carbon Sheets/CoP Hybrids with Enhanced Lithium and Potassium Storage 下载免费PDF全文
Jing Bai Baojuan Xi Hongzhi Mao Yue Lin Xiaojian Ma Jinkui Feng Shenglin Xiong 《Advanced materials (Deerfield Beach, Fla.)》2018,30(35)
Despite the desirable advancement in synthesizing transition‐metal phosphides (TMPs)‐based hybrid structures, most methods depend on foreign‐template‐based multistep procedures for tailoring the specific structure. Herein, a self‐template and recrystallization–self‐assembly strategy for the one‐step synthesis of core–shell‐like cobalt phosphide (CoP) nanoparticles embedded into nitrogen and phosphorus codoped porous carbon sheets (CoP?NPPCS), is first proposed. Relying on the unusual coordination ability of melamine with metal ions and the cooperative hydrogen bonding of melamine and phytic acid to form a 2D network, a self‐synthesized single precursor can be attained. Importantly, this approach can be easily expanded to synthesize other TMPs?NPPCS. Due to the unique compositional and structural characteristics, these CoP?NPPCSs manifest outstanding electrochemical performances as anode materials for both lithium‐ and potassium‐ion batteries. The unusual hybrid architecture, the high specific surface area, and porous features make the CoP?NPPCS attractive for other potential applications, such as supercapacitors and electrocatalysis. 相似文献
49.
Muhammad Asif Xin Gao Hongjie Lv Xinguo Xi Pengyu Dong 《International Journal of Hydrogen Energy》2018,43(5):2726-2741
Electricity and water from renewable hydropower plant are used as input for electrolysis unit to generate hydrogen, while CO2 is captured from 600 MW supercritical coal power plant using post-combustion chemical solvent based technology. The captured CO2 and H2 generated through electrolysis are used to synthesize methanol through catalytic thermo-chemical reaction. The methanol synthesis plant is designed, modeled and simulated using commercial software Aspen Plus®. The reactor is analyzed for two widely adopted kinetic models known as Graaf model and Vanden-Bossche (VB) model to predict the methanol yield and CO2 conversion. The results show that the methanol reactor based on Graaf kinetic model produced 0.66 tonne of methanol per tonne of CO2 utilized which is higher than that of the VB kinetic model where 0.6 tonne of methanol is produced per tonne of CO2 utilized. The economic analysis reveals that 1.2 billion USD annually is required at the present cost of both H2 production and CO2 abatement to utilize continuous emission of 3.2 million tonne of CO2 annually from 600 MW supercritical coal power unit to synthesize methanol. However, sensitivity analysis indicates that methanol production becomes feasible by adopting anyone of the route such as by increasing methanol production rate, by reducing levelised cost of hydrogen production, by reducing CO2 mitigation cost or by increasing the current market selling price of methanol and oxygen. 相似文献
50.
通过颗粒气泡脱附高速动态测试系统,研究了颗粒气泡脱附过程动力学。运用Image-Pro Plus图像处理软件测量颗粒气泡间接触角、三相润湿周边,计算颗粒气泡间毛细黏附力随颗粒运动时间的变化。结果表明:颗粒从气泡表面脱附主要分为气泡拉伸变形接触角增大和气泡滑动三相润湿周边减小两个阶段。气泡拉伸阶段,三相润湿周边固定在颗粒表面,接触角由平衡接触角增大到前进接触角;气泡滑动阶段,接触角保持不变,三相润湿周边滑动减小。毛细黏附力在气泡脱附过程中随接触角增大而增大,随三相润湿周边滑动而减小,当外力超过颗粒气泡间临界黏附力时,颗粒从气泡表面脱附。 相似文献